Adsorption of carbon dioxide on MIL53(Al), CuBTC and K- NaX zeolite
DOI:
https://doi.org/10.46291/ICONTECHvol4iss3pp30-42Keywords:
CO2 , adsorption, Ultrasound, NaX zeolite, MOFAbstract
CO2 adsorption on K exchanged NaX zeolites, and metal organic frameworks (MOFs), namely Cu-BTC and MIL53 (Al) was studied at 5 °C and 25 °C. Exchange via ultrasonic and traditional methods, was conducted at 50 °C and 70 °C. The maximum replacement of Na+ ion with K+ ion in the extra framework of zeolite was increased from 76% to 83% with increasing temperature from 50 °C to 70 °C in the ultrasonic method which is more effective than traditional one. Compared with the zeolites, the MOF adsorbents used in this work have higher Langmuir specific surface area values namely 1278, 1473 and about 1000 m2/g for MIL 53, Cu-BTC and zeolite adsorbents respectively. The resulting CO2 isotherms can be well represented by the Toth equation. Comparison of the isosteric heat of adsorption at zero loading shows that CO2 was adsorbed more weakly on MOFs than zeolites.
References
Yaghi, O. M.; O'Keeffe, M.; Ockwig, N. W.; Chae, H. K.; Eddaoudi, M.; Kim, J. Nature, 2003, 423, 705-714.
Zhao, Z. X.; Li, Z.; Lin, Y. S. Ind Eng Chem Res, 2009, 48, 10015–10020.
Xue, M.; Ma, S.; Jin, Z.; Schaffino, R. M.; Zhu, G. S.; Lobkovsky, E. B.; Qiu, S. L.; Chen, B. Inorg Chem, 2008, 47, 6825-6828.
Wang, B.; Cote, A. P.; Furukawa, H.; O'Keeffe, M.; Yaghi, O. M. Nature, 2008,453, 207-211.
Ramos, M. J.; Jimenez, V.; Funez, A.; Romero, A.; Sanchez, P. Valverde, J. L. Catal Lett, 2008, 125, 220-228.
Millward, A. R.; Yaghi, O. M. J Am Chem Soc, 2005, 127, 17998–17999.
Martin, C.; Tosi-Pellenq, N.; Patarin, J.; Coulomb, J. P. Langmuir, 1998, 14, 1775-1778.
Llewellyn, P. L.; Bourrelly, S.; Serre, C.; Filinchuk, Y.; Ferey G. Angew Chem. Int Edition, 2006, 45, 7751-7754.
Huang, H. Y.; Yang, R. T.; Chinn, D.; Munson, C. L. Ind Eng Chem Res, 2003, 42, 2427-2433.
Hayashi, H.; Cote, A. P.; Furukawa, H.; O'Keeffe, M.; Yaghi, O. M. Natural Material, 2007, 6, 501-506.
Harlick, P. J. E.; Tezel, F. H., Micropor Mesopor Mat, 2004, 76, 71-79.
Dunne, J. A.; Rao, M.; Sircar, S.; Gorte, R. J. ; Myers, A. L. Langmuir, 1996, 12, 5896-5904.
Bourrelly, S.; Llewellyn, P. L.; Serre, C.; Millange, F.; Loiseau, T.; Ferey, G. J Am Chem Soc, 2005, 39, 13519-13521.
Ferey, G.; Latroche, M.; Serre, C.; Millange, F.; Loiseau, T. Chemical Communications, 2003, 24, 2976-2977.
Walton, K. S.; Abney, M. B.; LeVan, M. D. Micropor Mesopor Mat, 2006, 91, 78-84.
Yang, C.; Xu, Q. H. Chem J Chinese U, 1996, 17, 1336-1340.
Barthomeuf, D. Micropor Mesopor Mat, 2003, 66, 1-14.
Erten-Kaya, Y. ; Cakicioglu-Ozkan F. Ultrason Sonochem, 2012, 19, 701–706.
Jasra, R.V. Tyagi, B. Badheka, Y.M.; Choudary, V.N. Bhat, T.S.G. Ind Eng Chem Res, 2003, 42, 3263-3272.
Yerkesikli, A.G. PhD, the Graduate School of Engineering & Science, İzmir Institue of Technology, TR, 2013.
Do, D.D. Adsorption Analysis: Equilibria and Kinetics, Imperial College Press: London, 1998.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2020 ICONTECH INTERNATIONAL JOURNAL
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
